Sustainable Process

Sodium Borate

The safety of our customers is extremely important to us. For that reason, we wanted to discuss one of the ingredients that’s used in some of our products: sodium borate. The EWG database lists this chemical as a “moderate concern” for users. The EWG database provides customers with a great “first glance” at an ingredient selection, but as with everything, the real story is more nuanced.

It’s important to remember that any chemical can be toxic. Things as innocent as table salt and water can, in high enough doses, be hazardous. The amount of exposure, and the method of exposure (inhalation, dermal, etc) are all critical factors in determining if something poses a genuine danger. Consider vinegar, as an example. Most people would agree that a tiny amount of vinegar sprinkled onto some types of food is desirable. However, most people would also agree that swallowing a bottle of vinegar would not be a good experience. The amount of exposure makes a difference.

We only use very low amounts of sodium borate (borax) in our products. Also, most of the safety warnings for sodium borate are related to inhaling the powdered dust, not from dermal exposure. We feel confident that our products are safe when used as directed. As we move into the future, we’ll continue to monitor safety findings and will make adjustments, for any ingredient, as new information becomes available. This matches our commitment to offering quality products that are safe and enjoyable to use. 

For a more in depth look as to how Sodium Borate is used in our products (and to further verify its safety) - read on below.

The safety of our customers is extremely important to us. For that reason, we wanted to discuss one of the ingredients that’s used in some of our products: sodium borate. The EWG database lists this chemical as a “moderate concern” for users. The EWG database provides customers with a great “first glance” at an ingredient selection, but as with everything, the real story is more nuanced.  

It’s important to remember that any chemical can be toxic. Things as innocent as table salt and water can, in high enough doses, be hazardous. The amount of exposure, and the method of exposure (inhalation, dermal, etc) are all critical factors in determining if something poses a genuine danger. Consider vinegar, as an example. Most people would agree that a tiny amount of vinegar sprinkled onto some types of food is desirable. However, most people would also agree that swallowing a bottle of vinegar would not be a good experience. The amount of exposure makes a difference.  

We only use very low amounts of sodium borate (borax) in our products. Also, most of the safety warnings for sodium borate are related to inhaling the powdered dust, not from dermal exposure. We feel confident that our products are safe when used as directed. As we move into the future, we’ll continue to monitor safety findings and will make adjustments, for any ingredient, as new information becomes available. This matches our commitment to offering quality products that are safe and enjoyable to use. 

For a more in depth look as to how Sodium Borate is used in our products (and to further verify its safety) - read on below.

Beeswax ❤️ Sodium Borate

So first, let’s talk about emulsifiers. Oils and water don’t like to mix. If you take a glass and fill it half way with water, then pour the other half full of vegetable oil, the oil and the water aren’t going to mix together. The oil is going to form its own layer, pooling on top of the water. The root cause of this is the molecular structure of the oil and water. Molecules only like to interact if they have things that they can offer each other. Similar molecules like to hang out together. Table salt for example, is very agreeable towards dissolving in water because it can offer water some attractive interactions and water can offer salt some beneficial interactions as well. Oil doesn’t have this same relationship with water, and so it’s going to shun the water molecules and stay all by itself.

Consider the following picture:

We start out with the vegetable oil (Phase B) floating on top of the water (Phase A). It just pools up. If we stir it vigorously (resulting in picture B), the oil droplets break up and scatter into the water. Remember though - oil doesn’t like water, so it does its best to get away from it. Since oils are less dense than water, it floats to the top, forming picture B. The only way to get this arrangement to permanently mix together, where the oil droplets are suspended in the water phase and stay suspended (picture D), is to add an emulsifier.

An emulsifier is a molecule that sort of likes to dissolve in water, and sort of likes to dissolve in oil. Different parts of the emulsifier molecule are hydrophilic (water-loving) and hydrophobic (water-hating). If you add an emulsifier to a mixture of oil and water and mix it up, you get a situation where the emulsifiers interact with the oil droplets and present a “friendly face” to the surrounding water molecules. That way the oil droplets no longer feel like they’re in a hostile environment. All the oil sees are the hydrophobic end of the emulsifier molecules, so they’re stable. All the water sees is the hydrophilic end of the emulsifier molecules, so they’re happy.

See the following picture.

So that’s how we get oil and water to mix together and stay stable. We add a small amount of an emulsifier, and it serves to stabilize the oil droplets, keeping them suspended in the water phase. This is the basis of all products which combine oil and water - culinary sauces, lotions, creams, etc. 

Emulsifiers are sometimes called for in other situations where technically everything is oil-based, but the oils get really picky and only like to interact with oils that are very similar. This situation happens but it’s less common. Most of the time if you see an emulsifier it’s because you have water and oils combined into one product. 

Ok, so let’s talk about beeswax and borax. The use of this combination of ingredients goes back quite a ways in history, back to when emulsifiers weren’t really in common usage. Lotions were so unstable that the oils and water would split within minutes, solutions had to be shaken before each use. A recipe was invented where someone mixed water, olive oil, and beeswax. They heated it up and then stirred it and got something kind of usable, but it wasn’t ideal. In the 1890s, a refinement came along where olive oil was replaced with mineral oil and they also added borax. 

Borax, or sodium borate, by itself is not an emulsifier. Beeswax by itself is not an emulsifier (this is a common mistake made by many beginning cosmetic chemists). Neither one has that key property of having both water-loving and water-hating sections to their molecular structure. When mixed together, however, they do form an emulsifier.

The answer lies in the composition of beeswax. Beeswax is a very complex product. It has over 300 different molecules present, including alcohols, esters, hydrocarbons, and importantly for this application, fatty acids. Fatty acids are molecules with an acid group at the end of a fatty carbon chain. The carbon chain likes to dissolve in oil; it’s hydrophobic. The acid end kind of likes to dissolve in water, but it’s not a strong enough tendency yet to act as an emulsifier. 

By adding the sodium borate, the fatty acids in beeswax (one of them in particular, cerotic acid) reacts with the sodium borate. Sodium borate is a base, so it wants to obtain a hydrogen atom. The cerotic acid is an acid, and so it wants to get rid of a hydrogen atom. This is a match made in heaven, so the sodium borate gets the proton from the fatty acid. This transforms sodium borate into boric acid and transforms the cerotic acid into a cerotate. This compound has a much stronger hydrophilic end now and combined with the fatty acid section, means that it’s perfect for use as an emulsifier. 

So the cerotic acid - present in about 13% in beeswax - becomes the emulsifying agent. It’s a very old-school approach to things. The sodium borate reacts with the beeswax and is transformed into the boric acid, so the amount of sodium borate left behind is very low. It’s the same type of acid-base chemistry as the old science project where you make a volcano by mixing vinegar and baking soda. In the end, the amount of vinegar left is very low, because it’s all reacted with the baking soda. It’s the same thing here.

If you have any more questions please feel free to reach out to us at hello@firsthandsupply.com